| 1 |  Samuel Sanchez Gonzalez (ESP) | Euskaltel - Euskadi | 4:42:47 |
| 2 |  Alexandr Kolobnev (RUS) | Katusha | 0:00:02 |
| 3 |  Fabian Wegmann (ALL) | Leopard - Trek | 0:00:07 |
| 4 |  Ryder Hesjedal (CAN) | Garmin - Cervelo | mt |
| 5 | Angel Madrazo Ruiz (ESP) | Movistar | mt |
| 6 |  Robinson Eduardo Chalapud Gomez (COL) | Colombia Es Passion - Cafe de Colombia | mt |
| 7 | Javier Moreno Bazan (ESP) | Caja Rural | mt |
| 8 |  Christophe Le Mével (FRA) | Garmin - Cervelo | mt |
| 9 | Joaquim Rodríguez Oliver (ESP) | Katusha | 0:00:13 |
| 10 |  Rinaldo Nocentini (ITA) | AG2R - La Mondiale | 0:00:16 |
| 11 | Francesco Bellotti (ITA) | Liquigas - Cannondale | mt |
| 12 | Sandy Casar (FRA) | La Française des Jeux | 0:00:19 |
| 13 | David Arroyo Duran (ESP) | Movistar | mt |
| 14 | Dominique Nerz (ALL) | Liquigas - Cannondale | 0:00:23 |
| 15 | Beñat Intxausti Elorriaga (ESP) | Movistar | mt |
| 16 | John Darwin Atapuma Hurtado (COL) | Colombia Es Passion - Cafe de Colombia | 0:00:32 |
| 17 | Iban Velasco Murillo (ESP) | Euskaltel - Euskadi | 0:00:33 |
| 18 | Igor Antón Hernandez (ESP) | Euskaltel - Euskadi | mt |
| 19 | Marzio Bruseghin (ITA) | Movistar | 0:00:37 |
| 20 | Mathieu Perget (FRA) | AG2R - La Mondiale | mt |
| 21 |  Vasil Kiryienka (BLR) | Movistar | 0:00:44 |
| 22 | Daniel Moreno Fernández (ESP) | Katusha | 0:05:32 |
| 23 | Xavier Tondo Volpini (ESP) | Movistar | 0:00:57 |
| 24 | Gorka Verdugo Marcotegui (ESP) | Euskaltel - Euskadi | 0:01:00 |
| 25 | Paolo Longo Borghini (ITA) | Liquigas - Cannondale | 0:01:32 |
| 26 |  Jakob Diemer Fuglsang (DAN) | Leopard - Trek | 0:01:38 |
| 27 |  Andy Schleck (LUX) | Leopard - Trek | mt |
| 28 | Fabio Felline (ITA) | Geox - TMC | mt |
| 29 | Fränk Schleck (LUX) | Leopard - Trek | mt |
| 30 |  Wesley Sulzberger (AUS) | La Française des Jeux | mt |
| 31 |  Thomas Peterson (E-U) | Garmin - Cervelo | 0:01:58 |
| 32 | Víctor Cabedo Carda (ESP) | Orbea | 0:02:03 |
| 33 | John Edilberto Martinez Montero (COL) | Colombia Es Passion - Cafe de Colombia | 0:02:41 |
| 34 | José Herrada Lopez (ESP) | Caja Rural | 0:03:07 |
| 35 | Marco Corti (ITA) | Geox - TMC | 0:03:08 |
| 36 | Jesus Rosendo Prado (ESP) | Andalucia - Caja Granada | 0:03:23 |
| 37 | Nairo Alexander Quintana Rojas (COL) | Colombia Es Passion - Cafe de Colombia | 0:04:51 |
| 38 | Alex Alberto Cano Ardila (COL) | Colombia Es Passion - Cafe de Colombia | mt |
| 39 | Rémi Pauriol (FRA) | La Française des Jeux | 0:05:32 |
| 40 | Mickaël Chérel (FRA) | AG2R - La Mondiale | mt |
| 41 | Egoitz Garcia Echeguibel (ESP) | Caja Rural | mt |
| 42 | Peter Stetina (E-U) | Garmin - Cervelo | mt |
| 43 | Alberto Losada Alguacil (ESP) | Katusha | mt |
| 44 | Antonio Piedra Perez (ESP) | Andalucia - Caja Granada | mt |
| 45 | Daniele Ratto (ITA) | Geox - TMC | mt |
| 46 | David Belda Garcia (ESP) | Burgos 2016 - Castilla y Leon | mt |
| 47 | Thomas Danielson (E-U) | Garmin - Cervelo | mt |
| 48 | Arnold Jeannesson (FRA) | La Française des Jeux | 0:06:13 |
| 49 | Francis Mourey (FRA) | La Française des Jeux | 0:06:18 |
| 50 | Pablo Lastras Garcia (ESP) | Movistar | 0:11:11 |
| 51 |  Murilo Antonio Fischer (BRE) | Garmin - Cervelo | mt |
| 52 | Mauro Finetto (ITA) | Liquigas - Cannondale | mt |
| 53 | Noel Martín Infante (ESP) | Orbea | 0:13:32 |
| 54 | Carlos Verona Quintanilla (ESP) | Burgos 2016 - Castilla y Leon | mt |
| 55 | Enrique Sanz Unzue (ESP) | Movistar | mt |
| 56 | Jens Voigt (ALL) | Leopard - Trek | mt |
| 57 | Aitor Galdos Alonso (ESP) | Caja Rural | mt |
| 58 | Jose Luis Roldan Carmona (ESP) | Andalucia - Caja Granada | mt |
| 59 | Diego Gallego Arnaiz (ESP) | Burgos 2016 - Castilla y Leon | mt |
| 60 | Ruben Perez Moreno (ESP) | Euskaltel - Euskadi | mt |
| 61 | Dimitri Champion (FRA) | AG2R - La Mondiale | mt |
| 62 | Simone Ponzi (ITA) | Liquigas - Cannondale | mt |
| 63 | Ricardo Garcia Ambroa (ESP) | Orbea | mt |
| 64 |  Maciej Paterski (POL) | Liquigas - Cannondale | mt |
| 65 | Mikel Bizkarra Etxeguibel (ESP) | Orbea | mt |
| 66 | Eloy Ruiz Pinto (ESP) | Andalucia - Caja Granada | mt |
| 67 | Aritz Etxebarria Etxebarria (ESP) | Orbea | mt |
| 68 | José Vicente Garcia Acosta (ESP) | Movistar | mt |
