| 1 |  Luis León Sánchez Gil (ESP) | Caisse d'Epargne | 5:47:13 |
| 2 |  Alexander Vinokourov (KAZ) | Astana | mt |
| 3 | Carlos Sastre Candil (ESP) | Cervélo Testteam | mt |
| 4 | Haimar Zubeldia Aguirre (ESP) | Radio Shack | 0:00:34 |
| 5 | Joaquim Rodríguez Oliver (ESP) | Katusha | 0:00:37 |
| 6 |  Ryder Hesjedal (CAN) | Garmin - Transitions | mt |
| 7 |  Robert Gesink (P-B) | Rabobank | mt |
| 8 |  Nicolas Roche (IRL) | AG2R - La Mondiale | mt |
| 9 | Samuel Sanchez Gonzalez (ESP) | Euskaltel - Euskadi | mt |
| 10 |  Richie Porte (AUS) | Saxo Bank | mt |
| 11 |  Greg Van Avermaet (BEL) | Omega Pharma - Lotto | 0:02:14 |
| 13 |  Chris Anker Sørensen (DAN) | Saxo Bank | mt |
| 14 | Javier Moreno Bazan (ESP) | Andalucía - Cajasur | mt |
| 15 |  Eros Capecchi (ITA) | Footon - Servetto | 0:03:43 |
| 16 |  Christian Knees (ALL) | Team Milram | mt |
| 17 | Rubén Plaza Molina (ESP) | Caisse d'Epargne | mt |
| 18 | Jose Ivan Gutierrez Palacios (ESP) | Caisse d'Epargne | mt |
| 19 | Imanol Erviti Ollo (ESP) | Caisse d'Epargne | mt |
| 20 | André Steensen (DAN) | Saxo Bank | mt |
| 21 | Inaki Isasi Flores (ESP) | Euskaltel - Euskadi | mt |
| 22 |  Christophe Le Mével (FRA) | La Française des Jeux | mt |
| 23 | David García Da Pena (ESP) | Xacobeo - Galicia | mt |
| 24 | Gorka Verdugo Marcotegui (ESP) | Euskaltel - Euskadi | mt |
| 25 | Damiano Cunego (ITA) | Lampre - Farnese Vini | mt |
| 26 | Morris Possoni (ITA) | Team Ineos | mt |
| 27 | Dries Devenyns (BEL) | Quick Step | mt |
| 28 | Giampaolo Caruso (ITA) | Katusha | mt |
| 29 | Daniel Moreno Fernández (ESP) | Omega Pharma - Lotto | mt |
| 30 |  Laurent Didier (LUX) | Saxo Bank | mt |
| 31 | Luis Pasamontes Rodriguez (ESP) | Caisse d'Epargne | mt |
| 32 | Jakob Diemer Fuglsang (DAN) | Saxo Bank | mt |
| 33 |  Robert Kiserlovski (CRO) | Liquigas - Doimo | mt |
| 34 | Ezequiel Mosquera Miguez (ESP) | Xacobeo - Galicia | mt |
| 35 | David Arroyo Duran (ESP) | Caisse d'Epargne | mt |
| 36 | Gustavo César Veloso (ESP) | Xacobeo - Galicia | mt |
| 37 | Igor Antón Hernandez (ESP) | Euskaltel - Euskadi | mt |
| 38 |  Levi Leipheimer (E-U) | Radio Shack | mt |
| 39 |  Volodymir Gustov (UKR) | Cervélo Testteam | mt |
| 40 | José Alberto Benitez Roman (ESP) | Footon - Servetto | 0:07:28 |
| 41 | Marco Pinotti (ITA) | Team HTC - Columbia | mt |
| 42 | Nicki Sørensen (DAN) | Saxo Bank | mt |
| 43 | Philippe Gilbert (BEL) | Omega Pharma - Lotto | mt |
| 44 | Marcos Garcia Fernandez (ESP) | Xacobeo - Galicia | mt |
| 45 | Jurgen Van De Walle (BEL) | Quick Step | mt |
| 46 |  Alexandr Kolobnev (RUS) | Katusha | mt |
| 47 | José Ángel Gómez Marchante (ESP) | Andalucía - Cajasur | mt |
| 48 | Juan Antonio Flecha Giannoni (ESP) | Team Ineos | mt |
| 49 | David De La Fuente Rasilla (ESP) | Astana | mt |
| 50 |  Stefan Denifl (AUT) | Cervélo Testteam | mt |
| 51 | David Lopez Garcia (ESP) | Caisse d'Epargne | mt |
| 52 | Anthony Roux (FRA) | La Française des Jeux | 0:09:01 |
| 53 | Niki Terpstra (P-B) | Team Milram | 0:09:44 |
| 54 | Juan Manuel Gárate Cepa (ESP) | Rabobank | mt |
| 55 | Valerio Agnoli (ITA) | Liquigas - Doimo | mt |
| 56 | Steven Kruijswijk (P-B) | Rabobank | mt |
| 57 | Ángel Vicioso Arcos (ESP) | Andalucía - Cajasur | mt |
| 58 | David Gutierrez Gutierrez (ESP) | Footon - Servetto | mt |
| 59 |  Gorazd Stangelj (SLO) | Astana | mt |
| 60 |  Martin Elmiger (SUI) | AG2R - La Mondiale | mt |
| 61 | Luca Mazzanti (ITA) | Katusha | mt |
| 62 | Francesco Gavazzi (ITA) | Lampre - Farnese Vini | mt |
| 63 | Markel Irizar Aranburu (ESP) | Radio Shack | mt |
| 64 | Tejay Van Garderen (E-U) | Team HTC - Columbia | mt |
| 65 | Jelle Vanendert (BEL) | Omega Pharma - Lotto | mt |
| 66 | Jan Bakelants (BEL) | Omega Pharma - Lotto | mt |
| 67 | Mickael Delage (FRA) | Omega Pharma - Lotto | 0:09:47 |
| 68 | Gonzalo Rabunal Rios (ESP) | Xacobeo - Galicia | 0:11:59 |
| 69 | José Luis Rubiera Vigil (ESP) | Radio Shack | mt |
| 70 | Ruben Perez Moreno (ESP) | Euskaltel - Euskadi | mt |
| 71 | Alan Perez Lezaun (ESP) | Euskaltel - Euskadi | mt |
| 72 | Maxim Iglinskiy (KAZ) | Astana | mt |
| 73 | Iñigo Cuesta Lopez De Castro (ESP) | Cervélo Testteam | mt |
| 74 | Jose Luis Arrieta Lujambio (ESP) | AG2R - La Mondiale | mt |
| 75 | Delio Fernandez Cruz (ESP) | Xacobeo - Galicia | mt |
| 76 | Vincenzo Nibali (ITA) | Liquigas - Doimo | mt |
| 77 | Daniele Pietropolli (ITA) | Lampre - Farnese Vini | mt |
| 78 | Marco Marzano (ITA) | Lampre - Farnese Vini | mt |
| 79 | Thibaut Pinot (FRA) | La Française des Jeux | mt |
| 80 | Arthur Vichot (FRA) | La Française des Jeux | mt |
| 81 |  John-lee Augustyn (AFS) | Team Ineos | mt |
| 82 | Francesco Bellotti (ITA) | Liquigas - Doimo | mt |
| 83 | Pedro Merino Criado (ESP) | Footon - Servetto | mt |
| 84 | Francesco Reda (ITA) | Quick Step | mt |
| 85 | Laurens Ten Dam (P-B) | Rabobank | mt |
| 86 |  Jorge Martín Montenegro Adaro (ARG) | Andalucía - Cajasur | 0:17:18 |
| 87 | Julien Loubet (FRA) | AG2R - La Mondiale | mt |
| 88 | Fabio Felline (ITA) | Footon - Servetto | mt |
| 89 | Josep Jufre Pou (ESP) | Astana | mt |
| 90 | Gert Dockx (BEL) | Team HTC - Columbia | mt |
| 91 | Serafín Martínez Acevedo (ESP) | Xacobeo - Galicia | mt |
| 92 | Andrey Kashechkin (KAZ) | Lampre - Farnese Vini | mt |
| 93 | Steven Cozza (E-U) | Garmin - Transitions | mt |
| 12 | Carlos Barredo Llamazales (ESP) | Quick Step | mt |
