| 1 |  Xavier Florencio Cabre (ESP) | Bouygues Télécom | 5.32.44 (40.57 km/h) |
| 2 |  Stefano Garzelli (ITA) | Liquigas | mt |
| 3 |  Andrey Kashechkin (KAZ) | Astana - Würth Team | mt |
| 4 |  Alexandre Botcharov (RUS) | Crédit Agricole | mt |
| 5 | Cristian Moreni (ITA) | Cofidis | mt |
| 6 | Mirko Celestino (ITA) | Team Milram | mt |
| 7 | Ricardo Serrano Gonzalez (ESP) | Kaiku | mt |
| 8 | Alejandro Valverde Belmonte (ESP) | Caisse d'Epargne | mt |
| 9 |  George Hincapie (E-U) | Discovery Channel Pro Cycling Team | mt |
| 10 | Franco Pellizotti (ITA) | Liquigas | mt |
| 11 | Manuele Mori (ITA) | Saunier Duval - Prodir | mt |
| 12 |  Thomas Lövkvist (SUE) | La Française des Jeux | mt |
| 13 | Riccardo Ricco (ITA) | Saunier Duval - Prodir | mt |
| 14 |  Theo Eltink (P-B) | Rabobank | mt |
| 15 | Denis Menchov (RUS) | Rabobank | mt |
| 16 | Andrea Moletta (ITA) | Gerolsteiner | mt |
| 17 | Pablo Lastras Garcia (ESP) | Caisse d'Epargne | mt |
| 18 | Marzio Bruseghin (ITA) | Lampre - Fondital | mt |
| 19 | Alexandr Kolobnev (RUS) | Rabobank | mt |
| 20 | Francisco Javier 'Patxi' Vila Errandonea (ESP) | Lampre - Fondital | mt |
| 21 |  Fränk Schleck (LUX) | Team CSC | mt |
| 22 | Juan Jose Cobo Acebo (ESP) | Saunier Duval - Prodir | mt |
| 23 | Andy Schleck (LUX) | Team CSC | mt |
| 24 | Evgeni Petrov (RUS) | Lampre - Fondital | mt |
| 25 | David Herrero Llorente (ESP) | Euskaltel - Euskadi | mt |
| 26 | Mikel Astarloza Chaurreau (ESP) | AG2R Prévoyance | mt |
| 27 |  Sylvain Calzati (FRA) | AG2R Prévoyance | mt |
| 28 | Juan Antonio Flecha Giannoni (ESP) | Rabobank | mt |
| 29 |  Matthias Russ (ALL) | Gerolsteiner | mt |
| 30 | Didier Rous (FRA) | Bouygues Télécom | mt |
| 31 | José Miguel Elías Galindo (ESP) | Relax - Gam | mt |
| 32 | Giuliano Figueras (ITA) | Lampre - Fondital | mt |
| 33 | David Moncoutie (FRA) | Cofidis | mt |
| 34 | Jose Ivan Gutierrez Palacios (ESP) | Caisse d'Epargne | mt |
| 35 | Daniel Moreno Fernández (ESP) | Relax - Gam | mt |
| 36 | Haimar Zubeldia Aguirre (ESP) | AG2R Prévoyance | mt |
| 37 | Jorge García Marín (ESP) | Relax - Gam | mt |
| 38 | Giovanni Visconti (ITA) | Team Milram | mt |
| 39 | Alexander Vinokourov (KAZ) | Astana - Würth Team | mt |
| 40 | Danilo Di Luca (ITA) | Liquigas | mt |
| 41 | Antonio Colom Mas (ESP) | Caisse d'Epargne | mt |
| 42 | José Luis Rubiera Vigil (ESP) | Discovery Channel Pro Cycling Team | mt |
| 43 | Davide Rebellin (ITA) | Gerolsteiner | mt |
| 44 | Inigo Landaluze Intxaurraga (ESP) | Euskaltel - Euskadi | mt |
| 45 | Carlos Sastre Candil (ESP) | Team CSC | mt |
| 46 | Iban Mayo Díez (ESP) | Euskaltel - Euskadi | mt |
| 47 | Luis Perez Rodriguez (ESP) | Cofidis | mt |
| 48 | Serguei Yakovlev (KAZ) | Astana - Würth Team | mt |
| 49 |  José Bento Azevedo Carvalho (POR) | Discovery Channel Pro Cycling Team | mt |
| 50 | Carlos Castaño Panadero (ESP) | Kaiku | mt |
| 51 | Vladimir Karpets (RUS) | Caisse d'Epargne | mt |
| 52 | Vincenzo Nibali (ITA) | Liquigas | 0.08 |
| 53 |  Simon Gerrans (AUS) | AG2R Prévoyance | 5.03 |
| 54 | José Alberto Benitez Roman (ESP) | Saunier Duval - Prodir | mt |
| 55 | Dmitri Fofonov (KAZ) | Crédit Agricole | mt |
| 56 | Jérôme Pineau (FRA) | Bouygues Télécom | mt |
| 57 |  Uros Murn (SLO) | Phonak Hearing Systems | mt |
| 58 |  Matej Jurco (SVK) | Team Milram | mt |
| 59 | Walter Beneteau (FRA) | Bouygues Télécom | mt |
| 60 |  Ryder Hesjedal (CAN) | Phonak Hearing Systems | mt |
| 61 | Alessandro Spezialetti (ITA) | Liquigas | mt |
| 62 | Rémi Pauriol (FRA) | Crédit Agricole | mt |
| 63 | Assan Bazayev (KAZ) | Astana - Würth Team | mt |
| 64 | Jonathan-Patrick 'Pat' McCarty (E-U) | Phonak Hearing Systems | mt |
| 65 | Ruben Oarbeascoa Ispizua (ESP) | Kaiku | mt |
